Product ID:EPA TCLP PESTICIDES MIX, 48139
MSDS Date:05/13/1994
FSC:6630
NIIN:00N066604
MSDS Number: BZSBM

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

4,7-METHANOINDENE, 1,4,5,6,7,8,8-HEPTACHLORO-3A,

CAS: 76-44-8

RTECS: PC0700000

Fraction By Weight: 0.1%

OSHA PEL 0.5 PPM, S

ACGIH TLV: 0.05 PPM, S

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

(ORAL,RAT) 40 MG/KG.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

5,8-DIMETHANONAPHTHALENE, 1,2,3,4,10,10-

CAS: 72-20-8

RTECS: IO1575000

Fraction By Weight: 0.1%

OSHA PEL 0.1 MG/M3, S

ACGIH TLV: 0.1 MG/M3, S

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

(ORAL,RAT) 3

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

4,7-METHANOINDAN, 1,4,5,6,7,8,8-HEPTACHLORO-,

CAS: 1024-57-3

RTECS: PB9450000

Fraction By Weight: 0.1%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

(ORAL,RAT) 62 MG/KG.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

CYCLOHEXANE, 1,2,3,4,5,6-HEXACHLORO-, GAMMA ISOMER;

CAS: 58-89-9

RTECS: GV4900000

Fraction By Weight: 0.1%

OSHA PEL 0.5 MG/M3 (MFR)

ACGIH TLV: 0.5 MG/M3 (MFR)

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHANE, 1,1,1-TRICHLORO-2,2-BIS(P-METHOXYPHENYL)-;

CAS: 72-43-5

RTECS: KJ3675000

Fraction By Weight: 0.1%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA).

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.5%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM;250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50:(ORAL,RAT) 5628 MG/KG (& SEE INGS)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. CONTAINS MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. HEADACHE, NAUSEA, GASTROINTESTINAL DISTURBANCES.
REPORTED MUTAGEN. REPORTED ANIMAL CARCINOGEN. CARCINOGENICITY -
INDEFINITE IN MAN. BLINDNESS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LST 15 MINS. CONT MD. SKIN:FLUSH
W/LG VOLS OF WATER. INHAL:IMMED MOVE TO FRESH AIR. IF BRTHG STOPS,
GIVE ARTF RESP. CONT MD. INGEST:NEVER GIVE ANYTHING BY MOUTH TO
UNCON PERS . NEVER TRY TO MAKE UNCON PERS VOMIT. GIVE 2 TBSPS OF
BAKING SODA IN GLASS OF WATER. PRESS FINGERS TO BACK OF TONGUE TO
INDUCE VOMIT. IMMED CONTACT MD.

Flash Point:50.0F,10.0C
Lower Limits:6%
Upper Limits:36%
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES. AVOID EYE OR
SKIN CONTACT. AVOID BREATHING VAPORS.
Other Precautions:THIS MATL IS INTENDED FOR R&D USE ONLY & MAY NOT BE
USED FOR DRUG, HOUSEHOLD/OTHER PURPOSES. IN ADDN, BURDEN OF SAFE
USE OF MATL RESTS W/YOU & THEREFORE, IT SHOULD BE HNDLD ONLY BY
QUALIFIED PERS TRAI NED IN LAB PROCS & GOOD SFTY PRACTICES.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK W/ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79 (H*2O=1)
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100%
Appearance and Odor:CLEAR, COLORLESS LIQUID.
Percent Volatiles by Volume:10

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.

Waste Disposal Methods:COMPLY W/ALL APPLICABLE FEDERAL, STATE & LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.